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Euromech=20 387

"Surface Slicks and Remote = Sensing of=20 Air-sea Interactions"

(7-9 April 1998) Windmill = Village,=20 Birmingham Road, Coventry CV5 9AL, = UK

Overview
Abstracts
Addresses
Information for=20 Authors
Letter from Neale=20 Thomas=20
Euromech 387=20 programme=20
Mail to Martin = Gade

Euromech 387 Proceedings Coming=20 Soon...


Editorial=20 Board:=20

=B7        =20    =20 Martin Gade (Universit=E4t=20 Hamburg, Germany)

=B7        =20    =20 Gerald M. = Korenowski=20 (Rensselaer = Polytechnic=20 Institute, NY, USA)

=B7        =20     John = C. Scott=20 (QinetiQ Ltd.,=20 UK)

=B7        =20     = Neale H.=20 Thomas (FRED Ltd.,=20 UK)


Overview

  1. Submitted=20 Papers=20
    1. <= SPAN=20 lang=3DEN-IE style=3D"mso-ansi-language: EN-IE">Mohamed = Atmane (interfacial=20 intermittence, 6 pp.) =20
    2. V. V. = Bakhanov (current effect = on nonlinear=20 surface waves, 5 pp.) =20
    3. <= SPAN=20 lang=3DEN-IE style=3D"mso-ansi-language: EN-IE">Simon = Boxall (visible and = near-infrared=20 measurements, 6 pp.) =20
    4. Nicole = Braun (artificial rain = &=20 slicks, 8 pp.) =20
    5. Peter = Dovey (radar observations = of surface=20 films, 13 pp.) =20
    6. <= SPAN=20 lang=3DEN-IE style=3D"mso-ansi-language: EN-IE">Kristian = Dysthe (surface renewal = and sea=20 slicks, 8 pp.) =20
    7. = Stanislaw=20 Ermakov (two=20 papers: damping of gravity-capillary waves, 7+6 = pp.)  =20
    8. Nelson = Frew (2 papers: = variability in=20 chemical composition, 11+9 pp.)  = =20
    9. Martin = Gade (two papers: = radar=20 measurements of slicks, 5+5 pp.)  =20
    10. Christine=20 Gommenginger=20 (LGA monitoring of slicks, 9 pp.) =20
    11. Harm = Greidanus (radar modelling = of=20 slicks, 13 pp.) =20
    12. Jochen = Horstmann (wind-speed from = SAR=20 imagery, 11 pp.) =20
    13. Heinrich=20 H=FChnerfuss=20 (slick morphology, 7 pp.) =20
    14. Paul = Hwang (wavenumber = spectra, 5=20 pp.) =20
    15. Bethan = Jones (Sea Empress = oil, 11=20 pp.) =20
    16. Gerald=20 Korenowski (two=20 papers: surfactant concentration distribution, 8+7=20 pp.)  =20
    17. <= SPAN=20 lang=3DEN-IE style=3D"mso-ansi-language: EN-IE">Susanne = Lehner (global = statistics from ERS=20 SAR, 17 pp.) =20
    18. Konstantin=20 Litovchenko=20 (oil spills on ALMAZ and ERS SAR, 11 pp.) =20
    19. <= SPAN=20 lang=3DIT style=3D"mso-ansi-language: IT">Giuseppe = Loglio (static and dynamic = surface=20 tension, 6 pp.) =20
    20. = Sean = McKenna (air-sea gas = transport,=20 11 pp.) =20
    21. <= SPAN=20 lang=3DEN-IE style=3D"mso-ansi-language: EN-IE">Boris = Noskov (multiple = scattering of=20 surface waves, 7 pp.) =20
    22. Efim = Pelinovsky (models of = internal=20 tides, 5 pp.) =20
    23. Stanislaw=20 Pogorzelski=20 (structural variability, 22 pp.) =20
    24. <= SPAN=20 lang=3DEN-IE style=3D"mso-ansi-language: EN-IE">John = Pullen (two papers: PIV = +=20 Lagrangian motions, 8+7 pp.)  =20
    25. = Uwe = Schimpf (air-sea gas = transfer, 9=20 pp.) =20
    26. Ted = Schlicke (air-sea gas = transfer, 8=20 pp.) =20
    27. Christian = Senet (GKSS; surface = tension=20 measurements, 8 pp.) =20
    28. = Jos=E9 da = Silva (slicks & = internal=20 waves, 10 pp.) =20
    29. David = Woolf (thermal = imagery, 10=20 pp.)  =

 

  1. Additional=20 Contributions
    1. Ian Robinson = (summary of=20 final discussion=20
    2. Nelson Frew = (tribute to Erik=20 Bock) =20
    3. Giuseppe Loglio (Carlo = Marangoni's=20 biography, 2 pp.) =20
    4. ... plus foreword(s) = =

 

Sum / papers : 35
Sum / existing = pages:=20 301
Sum / existing pages (starting right-hand): = 322 

 

(  =20 :=20 paper submitted;
   =20
:=20 one review received;
   =20
:=20 both reviews received;
   =20
:=20 reviews sent to corresponding authors;
   =20
:=20 updated paper submitted;
   =20
:=20 paper accepted   )


Abstracts

Note=20 to users who don't see the greek letter alpha here:  = &alpha;=20
Your=20 browser doesn't support greek characters and math symbols = specified in=20 HTML 4.0.  Some native HTML tags will appear in the text = below: =20 "&le;" means less or equal, "&Delta;" is an uppercase = greek delta,=20 "&pi;" is a lowercase greek pi.


Atmane, M. A. and J. George:
Interfacial = intermittence characterised by scalar and dynamic fields=20

Mass=20 transfer at a shear-free air-water surface in an agitated tank is = investigated=20 in this study. The free surface is submitted to a turbulent flow = generated in=20 the bottom of the tank using an array of micro jets. The mass transfer = is=20 simulated by creating a gradient of oxygen concentration in the water = phase. The=20 vertical and horizontal velocity components are measured, in the water = phase,=20 close to the surface using the LDA technique. The oxygen concentration = profiles=20 below the free surface are evaluated using a polarographic probe. Our=20 measurements show that the thickness of the oxygen boundary layer below = the=20 surface can be evaluated allowing a first estimate of the mass flux. A = physical=20 model based on the turbulent flux measurement, the surface renewal model = as well=20 as the interplay between different scales of the turbulent flow has been = proposed.

Bakhanov, V. V.:
Current effect on = nonlinear=20 surface waves

The transformation of = counterstream=20 nonlinear surface waves on a local perturbation of the stream is = investigated.=20 It is theoretically obtained, that surface-wave nonlinearity causes a = sharp=20 increase of surface-wave amplitude variability in time within a broad = frequency=20 band. Laboratory investigation results of various amplitude and = frequency=20 surface wave transformation in an inhomogeneous current field are given. = It is=20 found out, that the growing amplitude of a surface wave generated by a = wave=20 maker enhances variability of its parameters in the inhomogeneous = current field.=20 Theoretical calculations results are shown to agree well with the = experimental=20 basic singularities of the nonlinear surface wave transformation in the=20 inhomogeneous current field.

Boxall, S. R. and V. Byfield:
Oil = detection=20 and thickness estimates from radiance measurements at visible and near = infrared=20 wavelengths

This study develops the = technique of=20 optical measurement for the detection of oil in the marine environment. = A=20 theoretical model is proposed, which relates upwelling radiance from = surface oil=20 to the optical properties of the oil, the thickness of the oil layer, = and a=20 number of ancillary environmental parameters. The model is used to = interpret=20 optical image data from field experiments, and to provide estimates of = relative=20 oil thickness.

Braun, N., M. Gade, and P. A. Lange:=20
Laboratory measurements of artificial rain impinging on = slick-free and=20 slick-covered water surfaces

Laboratory measurements = with=20 artificial rain have been carried out in the wind-wave tank of the = University of=20 Hamburg, in order to gain better understanding of the radar = backscattering from=20 a (slick-free and slick-covered) water surface, particularly when it is = agitated=20 by strong rain. We used a coherent 9.8 GHz (X band) scatterometer at = different=20 polarizations and at an incidence angle of 28 degrees, a resistance-type = wire=20 gauge, and a two-dimensional laser slope gauge. A water surface area of = 2.3=20 m2 was agitated by strong artificial rain with a rain rate of = 160=20 mm/h and rain drops of 2.9 mm diameter. The wind-speed range used in the = present=20 investigation was between 2 and 10 m/s. A monomolecular = surface=20 film was produced by deploying oleyl alcohol on the water surface. Our = first=20 results of the analyses of the measured radar Doppler spectra and wave = amplitude=20 and slope spectra are presented. We show that (at a high rain rate of = 160 mm/h)=20 the surface slick affects the rain-induced increase of the surface = roughness (i.=20 e. the generation of crowns, cavities, stalks, ring waves, and secondary = drops)=20 less strongly than the wind-induced surface roughness (which is strongly = reduced=20 in the presence of the slick).

Dovey, PR., N.R. Stapleton, and J.C. = Scott.:=20
Radar observations of natural and artificial slicks=20

The current DERA slick = research=20 programme is aimed at understanding of the way slicks affect satellite = radar=20 images at low wind speed, principally to understand their role in = allowing the=20 detection of mesoscale ocean features.  The work examines the ways = in which=20 the ocean features affect the biogenic film distribution, and also = involves=20 `active' radar imaging experiments, by spreading artificial = ‘Emkarox’ slicks in=20 a variety of ocean surface conditions prior to imaging. This paper = presents=20 results covering a selection of the observations and experiments carried = out=20 utilising radar sensors onboard ERS-1 and SIR-C, and a multi-frequency = clifftop=20 glancing angle radar.

Dysthe, K. B.:
On surface renewal = and sea=20 slicks

[Excerpt from the = autor's=20 introduction in place of an abstract.]  In this paper we consider = some=20 simple case studies with surface film and substrate motion in search for = some=20 criteria for construction and destruction of a coherent film-covered = surface.=20 [...] We show in the following [...] that a slick can easily suppress = [...]=20 convective surface motion. Thus the heat transport through the sea = surface is=20 affected by surface films.

Ermakov, S. A., S. V. Kijashko, and J. C. = Scott=20
Damping of capillary-gravity waves due to films of insoluble = ordinary=20 surfactants and polymers

Laboratory measurements = of damping=20 of capillary-gravity waves due to organic films were carried out in a = wide range=20 of surfactant concentrations using a method of parametrically excited = surface=20 waves at frequencies from about 10 Hz to 30 Hz. The wave damping = coefficient was=20 measured for films of ordinary surface-active substances (oleyl alcohol = and=20 oleic acid), and for polymer films (polyoxyalkylene glycol - = “Emkarox”). It is=20 shown that the damping coefficient curves for the ordinary surfactants = exhibit=20 one peak at surface concentrations smaller than the concentration of a = saturated=20 monolayer; at larger concentrations the damping coefficient remains = practically=20 constant. The dependencies of the damping coefficient on surfactant=20 concentration for polymer films are strongly different. They are = characterized=20 by the existence of two maxima, one is a narrow peak at very low = concentrations=20 smaller than the concentration of a saturated monolayer and another is a = plateau-like maximum at larger concentrations. The elasticities of the = ordinary=20 and polymer films are estimated from the measured damping coefficient = using a=20 theory of wave damping for purely elastic films. The estimated dynamic=20 elasticities are shown to differ strongly, especially for saturated = monolayers,=20 from static elasticities, obtained from Langmuir trough=20 measurements.

Ermakov, S. A., , I.A.Sergievskaya, = E.M.Zuikova,=20 V.Yu.Goldblat, Yu.B.Shchegol’kov, N.Stapleton, and J.C.Scott =
Wave =20 tank study of phase velocities and damping of gravity-capillary wind = waves in=20 the presence of surface films

The wavenumber-frequency = spectrum of=20 gravity-capillary waves were measured using two optical spectrum = analysers and=20 an artificial gradient illuminator. It was found that the phase = velocities for=20 wavelengths smaller than 2-3 cm on clean water remain nearly constant = and do not=20 follow the dispersion relation of free surface waves. The phase = velocities were=20 found to increase with fetch, in the way that the phase velocities of = dominant=20 decimetric wind waves increase with fetch. This evidences that the wind = wave=20 spectrum contains nonlinear cm-mm-scale harmonics bound to the dominant = waves=20 and propagating with the phase velocities of the dominant waves. In the = presence=20 of films the observed phase velocities are closer to those of free = linear=20 gravity-capillary waves than they are in the case of clean water. This = can be=20 explained by the bound waves being more strongly damped than the free = waves. The=20 relation between bound and free waves is estimated from measurements of = phase=20 velocity. Wind ripple damping has been found to be maximum at = wavelengths around=20 5-7 mm. The last effect agrees with our field experiments using = artificial=20 slicks and can be explained qualitatively by a nonlinear = „cascade“ damping=20 mechanism, when the damping of decimetric dominant waves leads to strong = damping=20 of their cm-mm-scale nonlinear harmonics including damping of = „parasitic“=20 capillary ripples.

Frew, N. M., R. K. Nelson, and C. G. = Johnson:=20
Sea slicks: variability in chemical composition and surface=20 elasticity

Surface-active organic = matter=20 collected from the air-sea interface is examined using mass = spectrometry. The=20 mass spectra reveal significant spatio-temporal variability in the = chemical=20 composition of sea slick materials. This compositional variability leads = to=20 differences in observed surface pressure-elasticity=20 relationships.

Frew, N. M., R. K. Nelson, = and C. G.=20 Johnson:
Correlation studies of mass spectral patterns and = elasticity of=20 sea slick materials

Variations in the = chemical=20 composition of surfactants from natural sea slicks are compared to = variations in=20 surface elasticity using mass spectrometry, Langmuir film balance = measurements,=20 and multivariate statistical techniques. It is shown that the = information on=20 chemical class and molecular structure contained in the mass spectra is = strongly=20 correlated with measured static elasticity and can be used to estimate = film=20 elasticity at a given surface pressure.

Gade, M.:
On the imaging of = biogenic and=20 anthropogenic surface films on the sea by radar sensors.
Part = I:=20 damping ratio measurements by SIR-C/X-SAR and by an airborne = scatterometer=20

Radar signatures of sea = surface=20 films of different origin are studied, which have been acquired by the = airborne=20 multi-frequency/multi-polarization scatterometer HELISCAT as well as by = the=20 multi-frequency/multi-polarization Spaceborne Imaging Radar-C / = X-Band=20 Synthetic Aperture Radar ("SIR-C/X-SAR") during the two shuttle = missions in=20 1994. During both missions, controlled surface film experiments were = performed=20 in the German Bight, where various artificial biogenic substances as = well as=20 mineral oil were deployed on the sea surface, in order to study the = radar=20 signatures caused by the surface films of different visco-elastic = properties. We=20 show that, under high wind conditions (> 10 m/s), a=20 discrimination between the different kinds of surface films is very = difficult,=20 whereas at low to moderate wind speeds (&le; 5 m/s) a=20 discrimination seems to be possible.

Gade, M.:
On the imaging of = biogenic and=20 anthropogenic surface films on the sea by radar sensors.
Part = II:=20 results from modelling and from laboratory measurements=20

Radar signatures of sea = surface=20 films of different origin are studied, which have been acquired by the = airborne=20 multi-frequency/multi-polarization scatterometer HELISCAT during the = second=20 Spaceborne Imaging Radar-C / X-Band Synthetic Aperture Radar=20 ("SIR-C/X-SAR") mission in 1994, where a controlled surface film = experiment was=20 performed in the German Bight. Using results from the HELISCAT = measurements a=20 new model is developed for the wavenumber-dependent radar contrast at = high wind=20 speeds (> 10 m/s) caused by the surface films of different = visco-elastic=20 properties. In addition, results of laboratory experiments which were = carried=20 out in the wind-wave tank of the University of Hamburg are presented. We = show=20 that a different damping of bound and freely propagating surface waves = by a=20 monomolecular surface film occurs at certain wind-speed=20 ranges.

Gommenginger, C. P. and S. R. Boxall: =
Long-term=20 microwave radar monitoring of ocean slicks at low grazing angles=20

This paper proposes the = use of a=20 digital microwave marine radar system for the detection and monitoring = of=20 surfactant slicks at sea. The spatial, temporal and radiometric = resolutions of=20 this low grazing angle instrument are compared to those of satellite and = airborne radars traditionally used for oil pollution monitoring. = Experimental=20 evidence is presented in two artificial surfactant releases in the = coastal zone=20 which were successfully detected and tracked with a shore-based marine = radar.=20 The information contained in a long-term time-series of NRCS images is = explored=20 and its synergistic use with traditional satellite- and air-borne radar = data=20 discussed.

Greidanus, H.:
Radar modelling of = slicks based on=20 the "VIERS-1" wave spectrum

The VIERS-1 model = (Janssen et al.,=20 1998) was originally derived to describe ERS scatterometer measurements = over the=20 sea on a physical basis. This model is extended to include the = saturation range,=20 and it is used to derive equilibrium wave spectra and formulations for = the=20 relaxation toward that equilibrium, with and without slicks present. It = was=20 attempted to derive actual relaxation rates from the model, but this did = not=20 seem to lead to acceptable results. The extended VIERS model is combined = with a=20 radar imaging model originally designed for radar bathymetry, to yield=20 computations of radar transects through slicks. The resulting model is = capable=20 of quantitatively computing radar contrasts over a slick, showing = effects of=20 edge smoothing and apparent size increase due to finite relaxation = times. The=20 present work offers, however, no validation with actually measured=20 data.

Horstmann, J., W. Koch. S. Lehner, and W. = Rosenthal:=20
Mesoscale wind fields and their variation retrieved from = Synthetic=20 Aperture Radar aboard ERS-1/2

The synthetic aperture = radar (SAR)=20 aboard the European remote sening satellites (ERS-1 and ERS-2) acquires = images=20 that can be used to derive wind fields over the ocean surface. For this = purpose=20 an algorithm, based on Fast Fourier transformation, was developed to = retrieve=20 wind direction from wind induced streaks present in most SAR images. For = computation of wind speed an algorithm based on the C-band models CMOD4 = and=20 CMOD_IFR2 was evolved. To show the applicability of the algorithms, = images at=20 different geographical locations and under different meteorological and=20 oceanographical conditions were selected and compared to ground truth=20 measurements. At the German coast of the Baltic Sea a mesoscale wind = field was=20 retrieved from an ERS-1 SAR image and compared to the mesoscale = atmospheric=20 model GESIMA. Furthermore the different errors in wind speed due to = effects of=20 resolution, wind direction, and the accuracy of normalized radar cross = section=20 (NRCS) were estimated. The large coverage together with the high = resolution of=20 the ERS SAR-retrieved wind fields offer the opportunity to investigate = the=20 spatial variation of the boundary layer wind between scales of 2 to 100 = km. It=20 is shown that in this range there is no evidence of a spectral gap and = the=20 spectral energy decreases with increasing wavenumber. The decrease of = spectral=20 energy is according to the power law k-5/3 which is also = predicted by=20 the theory of two-dimensional isotropic = turbulence.

H=FChnerfuss, H., F. Hoffmann, J. Simon-Kutscher, = W.=20 Alpers, and M. Gade:
New chemical insights into structure and = morphology=20 of sea slicks and their geophysical implications =

The different morphology = of palmitic=20 acid methyl ester (PME) slicks spread from n-hexane and ethanol,=20 respectively, was studied by ‘Brewster Angle Microscopy’ = [BAM]. In the latter=20 case, already at large areas per molecule a foam-like structure is being = formed=20 on the water surface, i.e., a two-dimensional network which appears to = be=20 comparable with the morphological structure of biogenic sea slicks. In = line with=20 this assumption both the magnitudes of the radar backscatter damping = ratios as=20 well as the characteristics of the damping ratio/wavenumber curves = determined=20 for the PME slick spread from ethanol and for the biogenic slicks were = very=20 comparable, while in the presence of the PME slick spread from = n-hexane=20 lower damping ratios were determined. In the first instance, we were = able to=20 simulate the water wave damping characteristics of the biogenic sea = slicks very=20 well. Furthermore, the relaxation of alkanoic acid esters, which are = often being=20 found in biogenic sea slicks, was investigated by ‘Infrared=20 Reflection-Absorption Spectroscopy’ [IRRAS]. It turned out that = the ester group=20 is continuously hydrated and dehydrated during compression and dilation = on an=20 undulating water wave field. It can be safely assumed that the strong = water wave=20 damping induced by these chemical compounds is centrally related to this = phenomenon.

Hwang, P. A.:
Wavenumber spectra of = short=20 water waves in the ocean - a field case with internal waves and natural=20 slicks

Spatial measurements of=20 capillary-gravity waves in the ocean were collected using a scanning = slope=20 sensor mounted on a free-drifting, wave-following buoy. The spectral = analysis of=20 spatial measurements yields wavenumber resolution directly. The range of = wavelengths resolved from the optical sensor is from 0.4 to 6.2 cm. This = paper=20 investigates the variability of the spectral intensities of these=20 capillary-gravity waves under natural field conditions. For mild to = medium wind=20 speeds, the variation factor is typically between 1.5 to 2.5 in the = short=20 gravity wave regime, and between 2 to 4 in the capillary wave regime. = The=20 quantitative enhancement of the roughness contrast by natural slicks and = surface=20 current strains induced by internal waves is also=20 presented.

Jones, B.:
SAR imagery and visual=20 observations of the Sea Empress oil spill

A comparison has been = made between=20 the visual observations of surface oil and four synthetic aperture radar = (SAR)=20 images taken during the 'Sea Empress' oil spill. The study suggests that = the=20 optimum wind speed for the identification of thick surface oil is = 10 - 12=20 knots. At this wind speed, there is a distinction between the = backscatter=20 reduction due to sheen and thick oil. In lighter winds, sheen becomes=20 increasingly evident in the images and ist signal becomes = indistinguishable from=20 that of thicker oil.

Korenowski, G. M., E. VanWagenen, and A. Hirsa=20
Imaging Surfactant Concentration Distributions at the Air/Water=20 Interface
Part I: Surfactant Concentration Gradient on a = Laminar=20 Channel Flow

The surface specific = spectroscopic=20 probes of reflected second harmonic generation (SHG) and reflected sum = frequency=20 generation (SFG) have been successfully employed to measure surfactant = monolayer=20 concentration gradients on the ocean surface. Reflected SHG was adapted = for=20 areal measurements of monolayer concentrations using an intensified = pulse gated=20 CCD camera for detection and a dichromatic image splitter to allow for = signal=20 normalization and scaling. As a preliminary test prior to field use, the = imaging=20 probe was used to measure the surfactant concentration gradients for an=20 insoluble monolayer on a channel flow down stream of the Reynolds ridge. = The=20 resulting concentration measurements had a temporal resolution of 3 = nanoseconds=20 and spatial resolution of 0.21 millimeters or less per=20 pixel.

Korenowski, G. M., J. R. Saylor, E. VanWagenen, = J. S.=20 Kelley, M. E. Anderson, and E. J. Edwards:
Imaging Surfactant=20 Concentration Distributions at the Air/Water Interface
Part = II:=20 Insoluble Monolayer Concentrations on Standing Capillary Waves=20

Surfactant = concentrations at the=20 peaks and troughs of a standing capillary wave field were measured using = a=20 reflected second harmonic generation (SHG) imaging technique. The = results=20 revealed behavior that is consistent with a compaction of the insoluble=20 monolayer at the crests of the capillary waves and a dilation of the = monolayer=20 in the troughs. Each measurement was obtained using a single 3 = nanosecond laser=20 pulse, providing essentially instantaneous measurements of surfactant=20 concentration.

Lehner, S., J. Schulz-Stellenfleth, and J. = Horstmann:=20
Global distribution of sea surface features from ERS-2 SAR wave = mode=20 data

Since the launch of the = European=20 remote sensing satellites ERS-1 and ERS-2 in 1991 and 1995, synthetic = aperture=20 radar (SAR) images have been acquired over the oceans on a continuous = basis. A=20 global dataset of 5 km x 10 km complex SAR images, so = called=20 imagettes, which are acquired every 200 km along the orbit by the ERS-1 = and=20 ERS-2 satellites, are used to study sea surface features on a global = basis. So=20 far the European Space Agency (ESA) only provides coarsely gridded image = power=20 spectra (UWA spectra) which are used for ocean wave measurements at the = European=20 Center for Medium Range Weather Forecast (ECMWF). Using imagettes = instead of=20 image power spectra allows to study ocean surface features caused by = natural=20 slicks, sea ice or atmospheric processes. Different image parameters = like mean=20 intensity, coefficient of variation as well as energy, entropy of the=20 2-dimensional power spectrum and intensity variation in range direction = are used=20 to classify these phenomena. The results are compared to model data of = the=20 ECMWF. Furthermore the impact of these phenomena on scatterometer (SCAT) = wind=20 speed measurements is considered.

Litovchenko, K., and A. Ivanov:
Detection = of Oil=20 Slicks Parameters from ALMAZ-1 and ERS-1 SAR Imagery =

This paper presents the = results of=20 the oil spill observations using the Almaz-1 and ERS-1 SAR collected in = the=20 Norwegian Sea during the Dedicated Oil Spill Experiment in 1991. Three=20 artificial slicks were released from vessel on August 1991 and data on = sea and=20 weather conditions near the test area were collected. The test area was = imaged=20 by the Almaz-1 SAR and ERS-1 SAR. The analysis of acquired SAR images = shows that=20 the reduction of the backscatter from oil-covered sea surface ranged in = wide=20 limits: between few tens and 15 dB. For the first time an effect of an=20 intensification of wind waves both in the area of the slick and at the = windward=20 edge of the oil spill expressed as a magnification of the SAR image = brightness=20 has been detected. The increase of relative backscatter power was up to = 2.0 dB.=20 It is concluded that both Almaz-1 and ERS-1 SARs are the valuable tools = for oil=20 spill detection and localization but the detectability essentially = depended on=20 wind speed, sea state and age of spills.

Loglio, G., P. Pandolfini, R. Miller, B. = Noskov, U.=20 Tesei, A. M. Stortini, and R. Cini:
Static and dynamic surface = tension of=20 marine water: onshore or platform-based measurements by the oscillating = bubble=20 tensiometer

We illustrate = functionality and=20 performances of an oscillating bubble tensiometer, designed for the = measurement=20 of static and dynamic surface tension of marine water samples. The=20 instrumentation works in completely automatic mode. Semicontinuos = operation can=20 also be easily implemented. By virtue of its geometrical configuration, = the=20 apparatus shows a relative insensitivity to external disturbances, in = comparison=20 to other measurement techniques, and consequently it can be employed = even under=20 severe environmental conditions, such as those ones encountered onshore = or on=20 platform-based locations. We report experimental observations of the = dynamic=20 surface tension response to harmonic surface area changes, for samples = of sea=20 water and for a dilute aqueous solution of a standard surfactant. The = observed=20 results are considered useful for a physical characterisation of marine = water in=20 respect to interfacial ocean-atmosphere phenomena and processes. Also, = the=20 oscillating-air-bubble tensiometer mimics the real behaviour of the = bubbles=20 (ubiquitously present in the near surface of the oceans) and appears a = suitable=20 instrument for the assessment of the "availability to the air-water = interface"=20 of natural and man-made adsorption-film-forming organic=20 materials.

McKenna, S. P. and E. J. Bock: =
Physicochemical=20 effects of the marine microlayer on air-sea gas transport=20

Physicochemical = mechanisms of=20 enhanced gas transport across the air-sea interface are still not fully=20 understood, however, they are of critical relevance to many global=20 climatological processes. For example, the flux of CO2 (a = known=20 greenhouse gas) from the atmosphere into the ocean is important to the=20 environmental balance of the planet. Further, the need to interpret = air-sea gas=20 transfer on global scales requires that the key mechanisms of transport = be=20 relatable to remotely sensed information, such as imagery obtained from=20 satellite-borne radars. The ubiquity of surfactants in the ocean, = especially in=20 coastal zones (areas of significant phytoplankton concentration and = biological=20 productivity), strongly suggests their relevance to air-sea = interactions.=20 Surfactants are well known to impact surface and near-surface = hydrodynamics and=20 their role in reducing gas-transfer rates has been well documented. This = paper=20 reviews some of the history of these closely linked topics, focusing on = the=20 progress made in laboratory and field measurements. Sample results from = a=20 theoretical study in short wave propagation and laboratory experiments = involving=20 near-surface vortical flows are included to illustrate the important = role of=20 surfactant films on free- and near-surface hydrodynamics and the = implications=20 for air-sea gas exchange.

Noskov, B. A. and G. Loglio: =
Multiple=20 scattering of surface waves by two-dimensional colloid systems=20

Insoluble surface films = at the=20 air-water interface have been investigated by the capillary wave method = for many=20 years. However, it is only recently that a possibility to extract some=20 characteristics of their macroscopic structure by this technique has = been=20 realised. This work presents the results of a theoretical study of = surface wave=20 propagation along the liquid surface covered by a heterogeneous = insoluble=20 film.

Pelinovsky, E. and T. Talipova:
Models = of Intense=20 Internal Tides Observed by Remote Sensing

[Excerpt from the = autors'=20 introduction in place of an abstract.]  Internal tides, generated = through=20 the action of the barotropic tide forcing stratified water over sloping=20 topography, are a common feature of many continental slope and shelf = regions.=20 These internal tides are long internal waves most commonly seen at = semi-diurnal=20 periods and with wavelengths of 10's of km. In many instances these long = internal waves are observed to form instabilities seen as internal = bores, short=20 period waves, and soliton like waves. These short waves have periods on = the=20 scale of 10 minutes and wavelengths of 100's m. In most cases it appears = that=20 internal solitary waves are generated through topographic effects (sills = and=20 continental slopes) on tidal flow or on long internal waves such as = internal=20 tides. These energetic waves are important dissipation mechanisms for = the long=20 waves and provide a source of mixing energy that can move sediment and = increase=20 biological productivity. [...] In many cases the remote sensing was used = to=20 detect the internal wave field. Usually the Korteweg - de Vries equation = is=20 applied to explain the evolution of internal waves in the coastal zone = and its=20 manifestation on the sea surface. Last observations shows that internal = waves=20 reach large amplitudes and a weak nonlinear theory should be improved. = Here the=20 mathematical model of intense internal tide transformation is described. = It is=20 applied to calculate the orbital motions in the subsurface layer induced = by the=20 internal wave field.

Pogorzelski, S. J. and A. H. Kogut: =
Structural=20 variability of natural marine and inland waters films.
Part = I:=20 theoretical aspects

Theoretical aspects of = interpreting=20 force-area isotherms, and dynamic surface tension experiments on natural = water=20 surfactant films are discussed. The 2D virial equation of state applied = to the=20 isotherm plots, taken at an equilibrium film state, leads to the static = averaged=20 film parameters: a number of moles, the limiting specific area, and mean = molecular weight of surfactants composing the film. The 2D polymer film = scaling=20 theory can be adopted to the multicomponent film, by measuring the=20 high-frequency limit of the surface modulus E versus surface = pressure=20 (E =3D yp) with the = scaling=20 parameter y closely related to the surfactant miscibility and=20 vertically-segregated film structure. The film structure evolution is = also=20 predicted from the p - = A - isotherm = hysteresis vis=20 the entropy change DSc atributed to a certain loss of the = degrees of=20 feedom of the interfacial system during a compression-expansion cycle. A = time=20 scale and the nature of the film relaxation processes are derived from = dynamic=20 surface pressure-time plots applying the rheokinetic analysis for a = mixed=20 diffusion-kinetic adsorption model. Relaxation processes of the = interfacial=20 system lead to the surface viscoelasticity that can be expressed in the=20 framework of the diffusional viscoelasticity = model.

Pogorzelski, S. J. and A. H. Kogut: =
Structural=20 variability of natural marine and inland waters films.
Part = II:=20 experimental aspects

Natural surface film = experiments in=20 inland waters and shallow offshore regions of the Baltic and = Mediterranean Seas=20 were carried out in the time period 1990 - 1999 under calm sea = conditions using=20 a novel device for sampling and force-area studies. The sampler-Langmuir = trough-Wilhelmy filter paper plate system "cuts out" an undisturbed = film-covered=20 sea area (8 cm thick) to perform p - A studies without any initial=20 physico-chemical sample processing. The limiting specific area=20 Alim (268 - 3157 A2/molecule) and mean molecular = weight=20 (0.65 - 9.7 kDa) of microlayer surfactants were determined = from the=20 2D virial equation of state applied to the isotherms. Additional = information on=20 the film structure were derived from the entropy change DSc attributed to the p - A hysteresis, and the 2D = polymer film=20 scaling theory adopted to marine films. The stress-relaxation = measurements=20 revealed a two-step relaxation process at the interface with = characteristic=20 times t1 (1.1 - 2.8) and=20 t2 (5.6 - 25.6 seconds) suggesting the = presence=20 of diffusion-controlled and structural organisation relaxation = phenomena. The=20 obtained results demonstrate that natural films are a complex mixture of = biomolecules covering a wide range of solubilities, surface activity and = molecular weight with an apparent structural organisation exhibiting a = spatial=20 and temporal variability.

Pullen, J., A. Arnott, and C. Greated: =
Part I:=20 Particle image velocimetry study of the effect of surface active films = on=20 capillary gravity waves
Part II: Lagrangian motions near the = surface=20 of capillary gravity waves with surface active films =

[Excerpt from the = autors'=20 introduction in place of an abstract.]  The calming effect which a = film of=20 oil has on a water surface has been known for many centuries. Numerous=20 laboratory and field studies have shown that even films the thickness of = a=20 single molecule can have a significant effect on the initiation and = propagation=20 of surface waves. The general result of these films, whether formed by = natural=20 biological processes or mans' contamination, is to suppress wave = formation, the=20 practical significance of which is to alter the surface roughness of the = body of=20 water in question. In order to understand the effect that the surface=20 contaminant has on the wave generation process, an experimental = programme was=20 undertaken to examine in detail the motion of the water particles near = the=20 surface using the techniques of Particle Image (PIV) and Particle = Tracking=20 Velocimetry (PTV). The investigation was carried out along two lines:=20

           = ;            =         =20 I.          =20 The=20 investigation of the damping of wind generated waves by a thin soap film = using=20 cross-correlation digital PIV based on a novel, twin CCD camera=20 system.

           = ;            =      =20 II.          =20 Quantitatively measure the effect of = several=20 films on the elliptical trajectories of surface particles beneath waves=20 generated by a hinged paddle.

Schimpf, U., H. Hau=DFecker, and B. J=E4hne: =
Measurements of air-sea gas transfer using active and passive=20 thermography

In recent years, the = global climate=20 change and the growing pollution in atmosphere and oceans have drawn the = attention to small-scale transfer processes at the air/water interface.=20 Knowledge about the mechanisms of mass transfer is still marginal = because of the=20 lack of suitable experimental techniques. To obtain an insight into = these=20 processes new techniques for the quantitative investigation of gas = exchange have=20 been developed. In the following the Controlled Flux Technique = (CFT) is=20 presented, using heat as a proxy tracer for gases. The high spatial and = temporal=20 resolution of this unique technique allows studying key questions of = transfer=20 processes. Detailed laboratory measurements in the Heidelberg wind wave = facility=20 are reported. By switching the heat a the water surface periodically on = and off=20 , the temperature gradient across the interface is controlled and = estimated.=20 Given the net heat flux and the temperature gradient, the transfer = velocity for=20 heat is calculated and scaled to the gas transfer velocity for an = arbitrary gas.=20 The results are discussed and compared with conventional mass balance = methods=20 used in the facility.

Schlicke, T., J.M. Buick, A.D.Arnott, C.A. = Greated, and=20 N.H. Thomas:
Effect of Surface Films on Wave Amplitude and = Dispersion of=20 a Film by Breaking Waves

The presence of a = surface film has=20 been shown to alter the motion of surface capillary gravity waves [1,2]. = The=20 interaction between waves and a surface film depends on factors such as: = chemical composition of the film, its thickness, wave parameters coupled = with=20 bed slope and wind. A film acts to damp small scale waves, preventing = their=20 build up into larger waves which may break. Ironically, the beaking = process is=20 the primary mechanism for rapid dispersal of the film itself, therefore = an=20 understanding of the interaction is important. The work of [1,2] is = extended=20 using 2 approaches:
a) The mixing of a surface film after a break = event,=20 using the technique of Laser Induced Fluorescence (LIF) and
b) A = study of=20 how the effect of a film affects steep gravity waves with parasitic = capillary=20 waves riding on the leading face.
The work is ongoing, in this paper = some of=20 the effects of different breaking wave amplitudes on the mixing process = are=20 presented, along with preliminary work on how the surface film damps = waves and=20 affects the energy transfer between different length scales in the=20 waves.

Senet, C. M., J. Seemann, F. Ziemer:=20
Hydrographic parameter maps determined from optical image = sequences of=20 dynamic water surfaces

An experiment at the = wind wave of=20 the University of Hamburg was performed to retrieve optical image = sequences of=20 the water surface. The analysis of the image sequences based on a=20 three-dimensional Fast Fourier Transformation (3D FFT) is limited to = homogeneous=20 and stationary wave fields. This spectral description is limited to = stationary=20 and homogeneous wave fields and therefore other techniques which are = designed=20 for local scales are applied. For the examination of inhomogeneous wave = fields a=20 new method based on inverse and directional filter techniques is applied = to=20 retrieve hydrographic parameters on a local spatial scale. The results = show the=20 ability of the both methods to analyse and interpret multi-directional=20 homogeneous and inhomogeneous sea states.

da Silva, J. C. B., S. A. Ermakov, and I. S. = Robinson:=20
SAR imaging of slick modulated dynamic features=20

A method for remote = determination of=20 the presence of surfactants in the sea surface microlayer based on = observations=20 of internal wave (IW) signatures on satellite radar imagery is proposed. = It is=20 shown that small variations of surfactant concentration that occur on = shelf=20 zones caused by tidal flow can modulate the surface signatures of IWs, = producing=20 different signatures according to the local film concentration and wind = speed.=20 An analysis and classification of ERS SAR signatures of short-period IWs = on the=20 Iberian shelf is presented. Here it is shown that onshore propagating=20 short-period IWs exhibit different SAR signatures according to their = relative=20 position to the phase of the internal tidal wave. These transitions of = signature=20 mode can be explained by large scale variations of film parameters = produced by=20 the internal tidal waves. at low -to- moderate winds leading waves in = the IW=20 packets usually exhibit double sign signatures, which evolve presumably = to=20 negative sign signatures for the following waves in the packets. At very = low=20 near threshold winds the IW signatures can be in the form of the double = sign=20 type undergoing transition to positive sign signatures when compared to = the=20 background behind the IW packet. This is a consequence of different = threshold=20 wind speeds for excitation of Bragg waves at different film pressures. = We=20 present experimental evidence of an increase of unperturbed film = pressure in the=20 direction of the ranking order of solitons in a packet of short-period = IWs which=20 is predicted by the model and in agreement with measurements of film=20 elasticity.

Woolf, D. K. and N. Ward:
Thermal = imagery of=20 surface renewal phenomena

Processes within the sea = surface=20 microlayer have been relatively little studied considering their major = role in=20 air-sea interaction, especially gas exchange. This state of affairs can = be=20 explained by the inaccessibility of this very thin layer to most = methods. One of=20 the few suitable tools is radiometry which can probe a surface layer of = ~1=20 - 1000 micrometres according to the wavelength chosen. In = particular,=20 thermal imagery can be used to investigate turbulence impinging on the = sea=20 surface - "surface renewal patterns". Field measurements with thermal = imaging=20 cameras show evidence of fairly large-scale (~1 metre) organised = turbulent=20 structures. Thermal imagery is also a powerful tool in the study of = breaking=20 waves. Thermal images of breaking waves are characterised by a "hot"=20 high-emissivity crest ahead of a warm patch. Interpretation of field=20 observations remains difficult. Greater control on variables is possible = in the=20 laboratory. Laboratory experiments show that in dynamically weak = situations=20 (e.g., free convection), though the influence of eddies is readily = apparent,=20 these eddies do not appear to bring bulk water to the absolute surface. = Even=20 quite weak bubble plumes are highly effective in renewing the surface,=20 suggesting that they will influence the thermal signature of the sea = surface=20 following breaking waves, and may be an effective agent of air-sea gas = exchange.=20 Surface-active materials both influence the nature of surface renewal = and the=20 measurement process (through alteration of = emissivity).


Addresses

Arnott,=20 Alistair, Abteilung EV, Deutsches Zentrum fuer Luft- und Raumfahrt = (DLR),=20 G=F6ttingen, Germany
Atmane, Mohamed A., = Applied=20 Physics Laboratory, University of Washington, Seattle, WA, USA
Asher, = William, Applied=20 Physics Laboratory, University of Washington, Seattle, WA, USA
Bakhanov, Victor V., = Applied=20 Physics Laboratory Russian Academy of Sciences, Nizhny Novgorod, = Russia
Boxall, Simon R., = School of=20 Ocean and Earth Science, Southampton Oceanography Centre, Southampton,=20 UK
Braun, Nicole, = Institut=20 f=FCr K=FCstenforschung, GKSS Forschungszentrum, Geesthacht, = Germany
Buick, James M., CEAC; Aston = University,=20 Birmingham, UK
Byfield
, = Valborg,=20 School of Ocean and Earth Science, Southampton Oceanography Centre, = Southampton,=20 UK
Dovey, Peter = R.,=20 QinetiQ Inc., Winfrith Newburgh, Dorsey, UK
Dysthe, Kristian = B., Dept. of=20 Mathematics, University of Bergen, Bergen, Norway
Ermakov, Stanislav = A., Applied=20 Physics Laboratory Russian Academy of Sciences, Nizhny Novgorod, = Russia
Frew, Nelson M., Woods Hole = Oceanographic=20 Institution, Woods Hole, MA, USA
Gade, Martin, Institut = f=FCr=20 Meereskunde, Universit=E4t Hamburg, Hamburg, Germany
Gommenginger
, = Christine P.,=20 School of Ocean and Earth Science, Southampton Oceanography Centre, = Southampton,=20 UK
Greidanus, HSF = van=20 Wimersma, TNO Physics and Electronics Laboratory, JG Den Haag, The=20 Netherlands
Horstmann, Jochen,=20 Institut f=FCr K=FCstenforschung, GKSS Forschungszentrum, Geesthacht, = Germany
H=FChnerfuss, = Heinrich,=20 Institut f=FCr Organische Chemie, Universit=E4t Hamburg, Hamburg, = Germany
Hwang, Paul A., Naval = Research=20 Laboratory, Stennis Space Center, MS, USA
Ivanov, Andrei, P.P. = Shirshov=20 Institute of Oceanology, Russian Academy of Sciences, Moscow, = Russia
Jenkins, Alastair D., DNMI = Marine=20 Forecasting Centre, Bergen Norway
Jones, Bethan, = Marine Science=20 Laboratories, University of Wales, Bangor, UK
Klinke, Jochen, Scripps = Institution of=20 Oceanography, University of California, San Diego, CA, USA
Korenowski, Gerald M., Dept. of = Chemistry,=20 Rensselaer Polytechnic Institute, Troy, NY, USA
Lange, Philipp A., = Windwellenkanal=20 der Universit=E4t Hamburg, Bundesanstalt f=FCr Wasserbau, Hamburg, = Germany
Lehner, Susanne, Deutsches Zentrum = fuer=20 Luft- und Raumfahrt (DLR), IMF, Oberpfaffenhofen, Germany
Litovchenko,=20 Konstantin, Space Research Institute, Russian Academy of Sciences, = Moscow,=20 Russia
Loglio, = Giuseppe,=20 Dept. of Organic Chemistry, University of Florence, Florence, = Italy
McKenna, Sean P., Dept. of = Applied Ocean=20 Physics and Engineering, Woods Hole Oceanographic Insitution, Woods = Hole, MA,=20 USA
Noskov, Boris = A.,=20 Research Institute of Chemistry, St. Petersburg State University, Staryj = Petergof, Russia
Pelinovski, Efim, = Institute=20 of Applied Physics, Russian Academy of Sciences, Nizhny Novgorod,=20 Russia
Pogorzelski,=20 Stanislaw J., Institute of Experimental Physics, University of Gdansk, = Gdansk,=20 Poland
Robinson,=20 Ian S., School of Ocean and Earth Science, Southampton Oceanography = Centre,=20 Southampton, UK
Scott,=20 John C., QinetiQ Inc., Winfrith Newburgh, Dorsey, UK
Schimpf, Uwe,=20 Interdisciplinary Center for Scientific Computing, University of = Heidelberg,=20 Heidelberg, Germany
Senet, Christian M., = Institut f=FCr=20 K=FCstenforschung, GKSS Forschungszentrum, Geesthacht, Germany
da Silva, Jos=E9 = C.B., Instituto=20 de Oceanographia, Universidade de Lisboa, Lisboa, Portugal
Stapleton, Neil = R., QinetiQ=20 Inc., Winfrith Newburgh, Dorsey, UK
Thomas, N.H., FRED Ltd., = Birmingham,=20 UK
Woolf, David K., = James=20 Rennell Division, Southampton Oceanography Centre, Southampton, UK


Information=20 for Authors

Springer web = site for=20 authors
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Page = maintained by Martin=20 Gade - last update: October 23, = 2002
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